The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
Here we report on a polymer blend consisting of a soft-thermoplastic polyurethane (TPU) elastomer and a low melting temperature thermoplastic healing agent (Polycaprolactone, PCL) capable of repairing highly deformed cracks without the need for an external load. In this study, a blend containing 30wt% PCL (30PCL) was shown to exhibit two well-separated melting transitions thus enabling shape memory behavior. Moreover, upon heating to above PCL’s melting temperature the flow of PCL into an undeformed crack was shown to fill the crack void thus promoting self-repair. A combined healing mechanism relying on both shape memory and self-healing action was demonstrated. Through the simple action of mild heating (90C/30 minutes), fracture surfaces are brought into intimate contact through the action of shape memory recovery and subsequently healed. Healing efficiency was evaluated by comparing the tensile force restoration after healing of a highly deformed, notched sample to its behavior prior to notching. Here it was shown that the polymer blend exhibited full restoration of its originally mechanical integrity whereas the mechanical performance of pure TPU was only minimally restored (about 5%). This blend is based on thermoplastic ingredients and thus able to be converted using conventional melt processing. Applications of such blends can be extended to products prone to damage such as liner materials, protective coatings, sporting goods and shoe soles.
Dealing with plastics waste is a major issue confronted by the society. Single use items from water bottles to plastic packaging are major contributors to the generation of plastics waste globally. Innovative upcycling technology can transform a plastic with limited applications and a brief useful life into a different, more-durable resin with expanded potential uses and an extended lifetime. In this way, upcycling can help strengthen the circular economy and can help reduce the impact of single-use plastic applications on the environment.
Using propritary de-polymerization of recycled polyester, SABIC has introduced a more sustainable polyester products family containing up to 60% recycled materials. This new PBT and its compounds have similar purity and properties as virgin resin. Hence they are drop in for many virgin PBT or compounded products.
Chemistry, properties, and application for these sustainable polyester materials will be discussed. In particular, the application of ocean bound based resin in Dell computer fan housing will be highlighted.
Thermoplastic elastomers (TPEs) have been traditionally compounded and manufactured from raw materials based on fossil fuels. Current trends in marketplace abounds sustainability programs. TPEs are no exception to this trend. In a recent editorial, the authors stated “Through research and application, sustainability can evolve from a catchphrase to a societal one”. More than two decades ago the Brundtland Commission (formerly the World Commission on Environment and Development, WCED), deliberated sustainable development issue and gave a definition of sustainability: “Sustainable development meets the needs of the present without compromising the ability of future generations to meet their own needs.
Graphene is the thinnest known material and has the highest intrinsic strength of any material ever measured. We are posting an article to describe some of the interesting research on graphene and graphene-based polymer nanocomposites (GPNC) that is occuring. This article reviews how graphene is made, explain how single sheets can be dispersed in a polymer matrix to give plastics with interesting properties and where these works are being carried out.
Wood and plastic are best friends these days. They can be combined to give the aesthetics of wood with the added durability of plastic. Termed as wood/plastic composites - WPCs' are a relatively new family of thermoplastic composites based on wood-fibres and the commodity thermoplastics. The polymers used for WPCs' are the high volume, low cost, commodity thermoplastics - polyethylene, polypropylene and PVC.
Kim McLoughlin Senior Research Engineer, Global Materials Science Braskem
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Kim drives technology programs at Braskem to develop advanced polyolefins with improved recyclability and sustainability. As Principal Investigator on a REMADE-funded collaboration, Kim leads a diverse industry-academic team that is developing a process to recycle elastomers as secondary feedstock. Kim has a PhD in Chemical Engineering from Cornell. She is an inventor on more than 25 patents and applications for novel polyolefin technologies. Kim is on the Board of Directors of SPE’s Thermoplastic Materials & Foams Division, where she has served as Education Chair and Councilor.
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Gamini has a BS and PhD from Purdue University in Materials Engineering and Sustainability. He joined Penn State as a Post Doctorate Scholar in 2020 prior to his professorship appointment. He works closely with PA plastics manufacturers to implement sustainability programs in their plants.
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Tom Giovannetti holds a Degree in Mechanical Engineering from The University of Tulsa and for the last 26 years has worked for Chevron Phillips Chemical Company. Tom started his plastics career by designing various injection molded products for the chemical industry including explosion proof plugs and receptacles, panel boards and detonation arrestors for 24 inch pipelines. Tom also holds a patent for design of a polyphenylene sulfide sleeve in a nylon coolant cross-over of an air intake manifold and is a Certified Plastic Technologist through the Society of Plastic Engineers. Tom serves on the Oklahoma Section Board as Councilor, is also the past president of the local Oklahoma SPE Section, and as well serves on the SPE Injection Molding Division board.
Joseph Lawrence, Ph.D. Senior Director and Research Professor University of Toledo
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Dr. Joseph Lawrence is a Research Professor and Senior Director of the Polymer Institute and the Center for Materials and Sensor Characterization at the University of Toledo. He is a Chemical Engineer by training and after working in the process industry, he has been engaged in polymers and composites research for 18+ years. In the Polymer Institute he leads research on renewably sourced polymers, plastics recycling, and additive manufacturing. He is also the lead investigator of the Polyesters and Barrier Materials Research Consortium funded by industry. Dr. Lawrence has advised 20 graduate students, mentored 8 staff scientists and several undergraduate students. He is a peer reviewer in several journals, has authored 30+ peer-reviewed publications and serves on the board of the Injection Molding Division of SPE.
Matt Hammernik Northeast Account Manager Hasco America
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Matt Hammernik serves as Hasco America’s Northeast Area Account Manager covering the states Michigan, Ohio, Indiana, and Kentucky. He started with Hasco America at the beginning of March 2022. Matt started in the Injection Mold Industry roughly 10 years ago as an estimator quoting injection mold base steel, components and machining. He advanced into outside sales and has been serving molders, mold builders and mold makers for about 7 years.
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How to reference articles from the SPE Library:
Any article that is cited in another manuscript or other work is required to use the correct reference style. Below is an example of the reference style for SPE articles:
Brown, H. L. and Jones, D. H. 2016, May.
"Insert title of paper here in quotes,"
ANTEC 2016 - Indianapolis, Indiana, USA May 23-25, 2016. [On-line].
Society of Plastics Engineers, ISBN: 123-0-1234567-8-9, pp. 000-000.
Available: www.4spe.org.
Note: if there are more than three authors you may use the first author's name and et al. EG Brown, H. L. et al.