The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
The paper contains a brief review of the state-of-the-art in the stress-strain analysis (Structural Mechanics) of polymer coated optical glass fibers, with an emphasis on the analytical modeling.
In this paper, the Avrami and Urbanovici-Segal macrokinetic models were applied to describe the kinetics of isothermal crystallization from the melt state of syndiotactic polypropylene (sPP). Data analysis was carried out using a direct data-fitting procedure, in which the experimental data were directly fitted to each macrokinetic model using a non-linear multi-variable regression program. The results suggested that the Urbanovici-Segal model was the better of the two in describing the isothermal crystallization data of sPP.
An efficient and cost effective way of producing continuous fibre-thermoplastic matrix composites relies on the use of towpregs. Equipments are being developed for the production of the towpregs and also to manufacture pultruded profiles and filament winding structures. The properties of the composite products are determined and compared with conventional alternatives. An assessment is made on the influence of the processing conditions on the output and mechanical properties of glass fibre/polypropylene (GF/PP) composites.
E.C. Ferreira, N.M. Neves, R. Muschalle, A.S. Pouzada, May 2001
In the ejection stage of parts injection molded over cores the knowledge of the friction properties between the mould surface and the part are important to optimize the ejection system solution. The coefficient of friction depends strongly on the mould surface and the temperature at the moment of ejection. Prototype equipment was developed to measure the friction properties in as-molding conditions, and methods developed to perform the testing. Data will be presented for two thermoplastics (polycarbonate and polypropylene).
A.J. Pontes, R. Pantani, G. Titomanlio, A.S. Pouzada, May 2001
The prediction of ejection forces in tubular moldings (pipe fittings, cups, ..) is relevant for the optimization of the ejection systems in molds. An instrumented mold (pressure, temperature and force) for a tubular part was developed for measuring the actual ejection forces for two amorphous materials, polystyrene and polycarbonate. The ejection forces depend mostly on the holding pressure and the mould core temperature. The experimental data is used to validate a thermo-mechanical model that predicts the shrinkage and internal stresses.
As nylons 66 and 6 continue to grow in volume, they are beginning to take on the attributes of commodities, e.g., product interchangeability and price sensitivity. Producers are finding that high temperature nylons aimed at niche markets are sufficiently differentiated that they resist the trend toward commoditization while offering interesting volume potential in applications where value means more than price. This is an area where monomers make the difference and integrated producers have the field to themselves.
Terrence C. Caskey, Alan J. Lesser, Tom McCarthy, May 2001
Supercritical Carbon Dioxide (SC CO2) is used as a reversible plasticizing agent to promote solvent welding in highly oriented LLDPE films. Films are stacked in a quasi-isotropic fashion to enhance film properties in all directions. It is shown that, after processing, the oriented morphology and crystallinity are unchanged. The strength of the laminate interface is tested. Tensile properties of the laminated film are evaluated and tear resistance is measured using a single specimen J1C.
In this study, a small molecular phosphonate, dimethyl methyl phosphonate (DMMP), is investigated for its fortifier properties in addition to its diluent effects, using mechanical and thermal analysis techniques. This fortification is consistent with previously reported antiplasticization effects without the need for stiff, aromatic functionalities. Phosphonates are likewise known to enhance the flammability properties of polymers by reducing the heat release rate, resulting in a multi-functional additive.
Radiant heating by circulation of fluid through hose in or beneath flooring has become popular because of cost efficiency, particularly in new construction. Many systems in the field have been operated above recommended temperatures or used poor choices of circulating fluid and, as a result, show degradative effects and crack initiation. An additive package was developed that largely reversed these effects as indicated by dynamic mechanical measurements of elastic modulus.
The melt index of a single pellet is measured by combining experimental viscosity determination and simple modeling of the flow in the melt indexer. Special parallel plates are used to quantify the shear rheology of a 5 mg sample, the viscosity data is fit to a Power Law model, and the melt index is calculated. Results from this technique are compared to the results from actual melt index measurements for polyethylenes with a range of melt index values.
Alp Sarioglu, Daniel Schläfli, Jan-Anders E. Månson, May 2001
In this study, coextrusion flow in a new type of multi-layer extruder is analyzed by means of numerical simulation. This prototype extruder is based on a conical rotor-stator assembly. The extrusion of a range of polyethylenes and polypropylenes was investigated at various rotor speed regimes. The effect of die design and viscosity ratio between adjacent layers on the helicoidal flow is discussed.
With it being widely recognized and accepted that by raising customer retention rates by as little as 5%, benefits far beyond the obvious can be gleaned from repeat customers. Learn how companies are making efforts to develop brand loyalty and prospering while those that aren't are missing out on growth and profit opportunities.
Recent developments were oriented on the analysis of the mechanical performance at local (knit lines and welds) and bulk (molded part) areas, with the influence of molding and welding conditions. It has been found that for non-reinforced and reinforced nylon, the mechanical performance in the knit planes and welded areas are approximately equal to the mechanical performance of a base resin (matrix). The observations on similarities and differences in the formation of knit and weld lines are presented in Part I of this paper.
By using twin screw extruder, the compounding of PET, ZnO, and a modified polyolefin wax was carried out. As a result, the surface of ZnO was covered by a modified polyolefin wax, and, consequently, a fine-dispersed ZnO/PET compound was obtained without affecting the photocatalystic activity of ZnO. The plate, injection molded in 2mm thickness using this compound, had a good clarity and enabled to absorb the light of wavelength of under 360nm, completely.
M. Kontopoulou, J.A. Lee, L.C. Huang, W.E. Baker, A.M. Henderson, May 2001
Blends of Ethylene-Vinyl-Acetate copolymers (EVA) with metallocene based ethylene-a-olefin copolymers have been studied, with the purpose of exploring their properties and potential in film packaging applications. The effect of blend composition on rheological properties, heat seal, optical and tensile properties has been examined. It is shown that depending on their composition, these blends can offer a good balance of properties and processability.
A previously proposed model for the densification of powder compacts under isothermal conditions is extended to provide predictions of shrinkage and non-isothermal densification. This model, combined with predictions of bubble dissolution under non-isothermal conditions can provide a complete description of the shrinkage and densification of powder compacts. Model predictions compare favorably with experimental results.
Polymeric electrical insulation failures are due primarily to material composition, design, processing, service conditions or combinations thereof. Time to failure may be immediate, i.e., as manufactured, if specifications are not met. Others may not develop until after many years of service. Since life expectancy of electrical insulation is of the order of 40 years, failure in less time is considered unacceptable. Examples are given of many types of failure and their prevention for power distribution cable and for lower voltage applications.
Over the last five years, we have developed optical technologies for in-line monitoring of extrusion. We review two areas where we have succeeded in uncovering important concepts and phenomena by shedding light on processes that were previously unobservable. In the area of polymer blends, we have made real-time observations of blend microstructure during extrusion. we found conditions by which droplets could align in the vorticity axis. In the area of sharkskin and polyolefin extrusion, we have visualized how polymer process additives act and what causes sharkskin.
All OEMs will continue to outsource some manufacturing. Business machines, telecommunications, consumer and medical industries are following automotive's example. In 1998, companies farmed out 15% of all manufacturing. In 2000, they will outsource more than 40% (Hambrecht and Quist). This paper will describe in detail what is causing this trend and how it is influencing the plastics processing community. Trends will be discussed documented by survey results. Examples of value-added manufacturing companies are also provided.
This study investigates mechanical behavior and reversibility of dynamically vulcanized EPDM / i-PP blends. The composition of these elastomers dictates their morphology, which in turn controls their mechanical behavior. Six compositions are examined under dynamic loading. Dynamic mechanical responses are examined in terms of the Payne effect as a function of composition, cure state, and i-PP molecular weight. The Kraus model is applied and the resulting parameters are explained as a function of morphology.
Kim McLoughlin Senior Research Engineer, Global Materials Science Braskem
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Kim drives technology programs at Braskem to develop advanced polyolefins with improved recyclability and sustainability. As Principal Investigator on a REMADE-funded collaboration, Kim leads a diverse industry-academic team that is developing a process to recycle elastomers as secondary feedstock. Kim has a PhD in Chemical Engineering from Cornell. She is an inventor on more than 25 patents and applications for novel polyolefin technologies. Kim is on the Board of Directors of SPE’s Thermoplastic Materials & Foams Division, where she has served as Education Chair and Councilor.
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Gamini has a BS and PhD from Purdue University in Materials Engineering and Sustainability. He joined Penn State as a Post Doctorate Scholar in 2020 prior to his professorship appointment. He works closely with PA plastics manufacturers to implement sustainability programs in their plants.
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Tom Giovannetti holds a Degree in Mechanical Engineering from The University of Tulsa and for the last 26 years has worked for Chevron Phillips Chemical Company. Tom started his plastics career by designing various injection molded products for the chemical industry including explosion proof plugs and receptacles, panel boards and detonation arrestors for 24 inch pipelines. Tom also holds a patent for design of a polyphenylene sulfide sleeve in a nylon coolant cross-over of an air intake manifold and is a Certified Plastic Technologist through the Society of Plastic Engineers. Tom serves on the Oklahoma Section Board as Councilor, is also the past president of the local Oklahoma SPE Section, and as well serves on the SPE Injection Molding Division board.
Joseph Lawrence, Ph.D. Senior Director and Research Professor University of Toledo
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Dr. Joseph Lawrence is a Research Professor and Senior Director of the Polymer Institute and the Center for Materials and Sensor Characterization at the University of Toledo. He is a Chemical Engineer by training and after working in the process industry, he has been engaged in polymers and composites research for 18+ years. In the Polymer Institute he leads research on renewably sourced polymers, plastics recycling, and additive manufacturing. He is also the lead investigator of the Polyesters and Barrier Materials Research Consortium funded by industry. Dr. Lawrence has advised 20 graduate students, mentored 8 staff scientists and several undergraduate students. He is a peer reviewer in several journals, has authored 30+ peer-reviewed publications and serves on the board of the Injection Molding Division of SPE.
Matt Hammernik Northeast Account Manager Hasco America
A Resin Supplier’s Perspective on Partnerships for the Circular Economy
About the Speaker
Matt Hammernik serves as Hasco America’s Northeast Area Account Manager covering the states Michigan, Ohio, Indiana, and Kentucky. He started with Hasco America at the beginning of March 2022. Matt started in the Injection Mold Industry roughly 10 years ago as an estimator quoting injection mold base steel, components and machining. He advanced into outside sales and has been serving molders, mold builders and mold makers for about 7 years.
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How to reference articles from the SPE Library:
Any article that is cited in another manuscript or other work is required to use the correct reference style. Below is an example of the reference style for SPE articles:
Brown, H. L. and Jones, D. H. 2016, May.
"Insert title of paper here in quotes,"
ANTEC 2016 - Indianapolis, Indiana, USA May 23-25, 2016. [On-line].
Society of Plastics Engineers, ISBN: 123-0-1234567-8-9, pp. 000-000.
Available: www.4spe.org.
Note: if there are more than three authors you may use the first author's name and et al. EG Brown, H. L. et al.
